8.95 17.00(20°) 4.81(20°) 13.1(14.5°)
7.5 17.2(20°)
5.8
7.2
6.02 9.93 9.91(20°) 5.7 7.58
(71) Methoxybenzene
(72) Diethyl carbonate
(73) Fluorobenzene
(74) 1,1-Dichloroethene
(33) N,N-Dimethyl-acetamide
Name in Chinese 中文名
水 甲酰胺 乙二醇 甲醇 甲基甲酰胺 双乙二醇 三乙二醇 2-甲氧基乙醇 四乙二醇 甲基乙酰胺 乙醇 氨基乙醇 乙酸 丙醇 苄醇 丁醇 戊醇 异戊醇 异丁醇 异丙醇 2-丁醇 环己醇 碳酸丙二酯(丙烯酸) 2-戊醇 硝基甲烷 3-戊醇 乙腈 二甲亚砜(DMSO) 苯胺 环丁砜(四氢噻吩砜) 乙酸酐 二甲基甲酰胺(DMF) 二甲基乙酰胺
(92) Carbon disulfide
(93) Tetrachloromethane
(94) Triethylamine
(95) Tri-n-butylamine
(96) cis-Decahydro-naphthaline
(97) n-Heptane
(98) n-Hexane
(99) n-Pentane
14545
7.6
0.648
16.7
117.9
1.3719
5.6
0.617
-126.2
97.15
1.3856
5.5
0.608
-15.3
205.45
1.5404
5.5
0.602
-88.6
117.7
1.3993
5.8
0.568
-78.2
138
1.41
5.7
0.565
-117.2
130.5
1.4072
6.1
(75) Chlorobenzene
(76) Bromobenzene
(77) Ethoxybenzene
(78) lodobenzene
(79) 1,1,1-Trichloroethane
(80) 1,4-Dioxane
(81) Trichloroethene
(82) t-Butyl methyl ether
1.3658 1.3877 1.4707(25°)
1.3819
11.9
0.463
-75
115.3
1.4104
5.5
0.46
-43.8
81.6
1.3441
11.8
0.444
18.5
189
1.4793
13.5
0.42
-6
184.4
1.5863
5.0
0.41
28.45 287.3 (dec.) 1.4816(30°) 16
0.407
-73.1
140
1.3904
9.4
0.404
-60.4
153
1.4305
10.8
0.401
-20
166.1
1.4384
12.4
0.401 0.389 0.364 0.355 0.355 0.352 0.349 0.333 0.327 0.327 0.324 0.321 0.321 0.318 0.318 0.315 0.315 0.309 0.306 0.302 0.287 0.281 0.269 0.269 0.269 0.265 0.259 0.256 0.253 0.247 0.244
(83) Piperidine
(84) Diethylamine
(85) Diphenyl ether
(86) Diethylether
(87) Benzene
(88) Di-n-propyl ether
(89) Toluene
(90) 1,4-Dimethylbenzene
(91) Di-n-butyl ether
28.86(20°) 12.47 37.6 32.2 20.56 36.12 12.9 25.2 10.37
18.51(20°) 34.78 5.78
15.38(20°) 23.6 7.42 296
15.87(30°) 8.93 17.39 12.91 6.68
16.10(20°) 13.11(20°) 10.0(18°)
pp.4 08-
Tabl e A-
No. (1) Water
Solvent Name 溶剂名称
(2) Formamide
(3) 1,2-Ethanediol
(4) Methanol
(5) N-Methylformamide
(6) Diethylene glycol
(7) TriethyIene glycol
97.35 82.3 225.5 202 56.1 230 116.9 191.1 83.5 79.6 210.8 102 102.3 175.2 128.9 233 94.2 39.6 202 115.25 56.9 155.65 117.4 573 237.1 102 61.2 106.3 216 125.25 159.8 (dec.)
mp (°C) 熔点
0
bp (°C) 沸点
100
nD20 (g)
u (f)
1.3335.9源自0.7992.55
210.5
1.4475
11.2
0.79
-12.6
197.5
1.4318
7.7
0.762
-97.7
64.5
1.3284
5.7
0.722
-3.8
180-185
1.4319
12.9
0.713
-7.8
4.33 2.82(20°)
5.42 4.82(20°)
5.62 5.4 4.22(20°) 4.49(20°) 7.25(20°) 2.21 3.42(16°) 4.5(20°) 5.8(20°) 3.78 3.69(20°) 4.2 2.27 3.39(26°) 2.38 2.27(20°) 3.08(20°) 2.64(20°) 2.23 2.42(20°)
(100 )
Cyclohexane
a Tb hCe. Rc eic Md elt Be oili Rf ela Dg ipo Refr
苯甲醚 碳酸二乙酯 氟苯 1,1-二氯乙烯 氯苯 溴苯 苯乙醚 碘苯 1,1,1-三氯乙烷 杂环己烷(二噁烷) 三氯乙烯 叔丁基甲醚 哌啶 二乙基胺 二苯醚(苯酚醚) 乙醚 苯 二丙醚 甲苯 对二甲苯 二丁醚 二硫化碳 四氯甲烷 三乙基胺 三丁基胺 顺十氢萘 正庚烷 正己烷 正戊烷 环己烷
(17) 1-Pentanol
(18) 3-Methyl-1-butanol, Isoamyl alcohol
(19) 2-Methyl-1-propanol, Isobutyl alcohol
(20) 2-Propanolm)
(21) 2-Butanol
(22) Cyclohexanol
(23) Propylene carbonate
2.20(20°) 1.92(20°)
1.88 1.84(20°) 2.02(20°)
h NI Yo.r Mk Ja.r Fl Y. . MmaYr. Mn aJ.r Fo .B. Jp.M. Bq rJe. Fr C. . As gJa. Ft K. . M.
ET (h-Planck常数) 极性经验参数 1
245.7
1.4475
7.7
0.704
-4.3
288
1.4558
10.0
0.667
-85.1
124.6
1.4021
6.8
0.664
-6.2
327.3
1.4577
10.8
0.657
30.6
206.7
1.4253(35°) 14.2
0.654
-114.5
78.3
1.3614
5.8
0.651
10.5
170.95
15 64.92 13.71 35.94 13.35 35.94 46.45 6.71(30°) 43.3(30°) 20.7(19°) 36.71 37.78
(34) Propanenitrile (35) 2-Methyl-2-propanol, t-Butanol (36) 1.3-Dimethyl-imidazolidin-2-one, DMEU (37) 1-Methylpyrrolidin-2-one (38) Acetone (39) 1.3-Dimethyl-2-oxo-hexahydropyrimidine, DMPU (40) 1,2-Diaminoethane (41) Cyanobenzene (42) 1,2-Dichloroethane (43) 2-Butanone (44) Nitrobenzene (45) 2-Methyl-2-butanol, t-Pentyl alcohol (46) 2-Pentanone (47) Tetramethylurea (48) Morpholine (49) Hexamethylphosphoric acid triamide, HMPT (50) 3-Methyl-2-butanone (51) Dichloromethane" (52) Acetophenone (53) Pyridine (54) Methyl acetate (55) Cyclohexanone (56) 4-Methyl-2-pentanone (57) 1,1-Dichloroethane (58) Quinoline (59) 3-Pentanone (60) Chloroform (61) 3,3-Dimethyl-2-butanone (62) Triethylene glycol dimethyl ether (63) 2,4-Dimethyl-3-pentanone (64) Diethylene glycol dimethyl ether