2.2 Capture of the Free Radical by the Monomers
• • • • •
2.3 Propagation 2.4 Termination Reaction 2.5 Copolymerization 2.6 Inhibition and Retardation 2.7 Donor-Acceptor Complexes in Copolymerization • 2.8 Polymer5ization of Complexes With Lewis Acids
– Author: Malcom P. Stevens
Contents
1. Introduction and Physical Properties of Polymers • Introduction
• Physical Properties of Polymers
– – – – – – Structure and Property Relationship in Organic Polymers Amorphous and Crystalline arrangements Effect of Chemical structure upon Physical Properties Solution of Polymers Molecular weights and Molecular weight distributions Steric Arrangement in Macromolecules
高等高分子化學 Advanced Polymer Chemistry
李文福 教授
References
• Principles of Polymer Chemistry (second Edition)
– Author: A. Ravve
•
Polymer Chemistry - an Introduction(3rd ed)
4.1 Mechanism and Kinetics of Step Growth Polymerization 4.2 Polyesters 4.3 Polyamides 4.4Aromatic Polyamide-Imides and Aromatic Polyester-Imides 4.5 Polyimides 4.6 Polyethers
Lectures 1 and 2
Definitions
• Definition：poly (很多) mer (unit) 由很多repeating unit 組成 • 最簡單的polymer：linear Polyethylene • 分子量＞10000 可稱 polymer • 分子量＜10000 稱 oligermer • Molecular weight (Mw) • Chain length • Degree of Polymerization
4.7 4.8 4.9 4.10 4.11 4.12
Polyurethanes Epoxy Resins Phenol-Formaldehyde Resins Silicon Polymers High Performance Polymers Dendrimers and Polyrotaxanes
3.Ionic Chain-Growth Polymerization
3.1 Chemistry of Ionic Chain-Growth Polymerization 3.2 Kinetic of ionic Chain Growth Polymerization 3.3 Cationic Polymerization
2.9 Controlled/”Living” Polymerization 2.10 Atom Transfer radical Polymerization 2.11 Special Types of Controlled/ “Living” polymerization 2.12 Kinetic of Controlled/ “Living” Polymerization
• Classification • Carothers • Addition polymer • Condensation polymer • Flory • Step-growth polymer • Chain-growth polymer
Lectures 1 s
• • • • • star-shaper polymer comb-shaper polymer ladder polymer Semi-ladder polymer network polymer
• Homopolymer：單一monomer聚合的 polymer • Copolymer A+B • Rendom ABAAABABA • Alternating ABABABABAB • Block AAAAAAAABBBBBBBBAAAAAAA • Graft 接枝(多用於表面處理)
– Two electron Transposition Initiation Reaction – One Electron Transposition Initiation Reaction
3.4 Anionic Polymerization of Olefins
4. Step Growth Polymerization
2. Free-Radical Chain-Growth Polymerization 2.1 Free-Radical Chain-Growth Polymerization Process
– Kinetic Relationship in Free-Radical Polymerization – Reaction Leading to Formation of Initiating Free-Radicals