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邻苯二甲酰亚胺转化成邻苯二甲酰胺 Reaction_04_01_2016_105133

1. Single Step92%OverviewSteps/StagesNotes

1.1R:NH3, R:H2O, S:H2O

Reactants: 1, Reagents: 2, Solvents: 1, Steps:

1, Stages: 1, Most stages in any one step: 1

ReferencesAmmonolysis of cyclic aromatic acid imidesBy Arkhipova, I. A. et alFrom Zhurnal Organicheskoi Khimii, 27(3),621-8; 1991

CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactionsfrom CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformationsdatabase compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproducedunder license. All Rights Reserved.

2. Single Step

81%OverviewSteps/StagesNotes

1.1R:NH3, S:H2O, 24 h, rt

literature preparation, Reactants: 1, Reagents:

1, Solvents: 1, Steps: 1, Stages: 1, Moststages in any one step: 1

ReferencesONSH: Optimization of OxidativeAlkylamination Reactions through Study ofthe Reaction Mechanism

By Verbeeck, Stefan et alFrom Journal of Organic Chemistry, 75(15),5126-5133; 2010

Experimental Procedure

SciFinder®Page 1 1H NMR (DMSO-d6): δ 7.69 (s, 2H), 7.43-7.49 (m, 4H), 7.31 (s, 2H). 13C NMR (DMSO-d6) δ: 170.7,136.7, 129.7, 128.1. HRMS (ESI) for C8H9N2O2+ [M + H]+ , calcd 165.0659, found 165.0645.

CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactionsfrom CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformationsdatabase compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproducedunder license. All Rights Reserved.

3. Single Step

81%OverviewSteps/StagesNotes

1.1R:NH3, S:H2O, 24 h, rt

literature preparation, Reactants: 1, Reagents:

1, Solvents: 1, Steps: 1, Stages: 1, Moststages in any one step: 1

ReferencesONSH: Optimization of OxidativeAlkylamination Reactions through Study ofthe Reaction Mechanism

By Verbeeck, Stefan et alFrom Journal of Organic Chemistry, 75(15),5126-5133; 2010

CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactionsfrom CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformationsdatabase compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproducedunder license. All Rights Reserved.

4. Single Step

OverviewSteps/StagesNotes

SciFinder®Page 2 1.1R:NH

3

Reactants: 1, Reagents: 1, Steps: 1, Stages:

1, Most stages in any one step: 1

ReferencesPhthalocyanine green pigment fine cleanproduction process

By Yang, Hanzhou and Zhu, JiFrom Faming Zhuanli Shenqing, 104804465,29 Jul 2015

CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactionsfrom CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformationsdatabase compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproducedunder license. All Rights Reserved.

5. Single Step

OverviewSteps/StagesNotes1.1Reactants: 1, Steps: 1, Stages: 1, Most stagesin any one step: 1

ReferencesSynthesis and hypolipidemic activity of 3-imino-1-oxoisoindolines in rodents

By Murthy, Akula R. K. et alFrom Pharmaceutical Research, 4(1), 21-7;1987

CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactionsfrom CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformationsdatabase compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproducedunder license. All Rights Reserved.

SciFinder®Page 3

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