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论文题目:水杨醛及其席夫碱类 二芳基乙烯的合成及性质研究
答辩内容
研究内容 科研成果 进度安排 致谢
第一章：水杨醛二芳烯的合成及 性质研究
第二章：含氨基苯基硫脲的水杨醛 席夫碱二芳烯的合成及其性质研究
A
B
A
B
C
D
A
B
C
A
B
C
D
E
F
500 400 300 200 100
0.24
R = -0.9927
3
A/B = 1.1*10
0.22
0
F /(F-F )
0.20
0
0.18
0.16
0.14
5000
6000 7000 8000
3+ -1
-1
[Al ] (mol L)
9000 10000
C
A B
A B
第四章：含喹啉类二芳烯的合成 及其性质研究
Absorbance
0.8 Vis UV
0.6
0.4
0.2
1o'
UV
0.0
300
400
500
600
700
800
Wavelength (nm)
C
Absorbance (AU)
Absorbance (AU)
0.8
TBAH HCl 0.6
1c'
0.4
0.2
1c
0.0 300 400 500 600 700 800 900 1000 Wavelength (nm)
B
0.8
0.6 Vis
0.4
1c'
0.2
0.0
1o'
300 400 500 600 700 800 900 1000 Wavelength (nm)
D
Emission intensity (a.u.)
Emission intensity (a.u.)
500 HCl TBAH
400
1o
300
200
100
600 500 400 300 200 100
0 400
Vis UV
450
500
550
Wavelength (nm)
C
A
B
0.4
Free and other metal ions
1.0
0.3 0.8
0.2
0.6
Absorbance A/A
0
0.1 Cu2+
0.0
500
600
0 500
120 100
80 60 40 20
0 500
HCl TBAH
1c
1c'
550
600
650
Wavelength (nm)
B
Vis
1o'
1c'
550
600
650
Wavelength (nm)
D
700 7ห้องสมุดไป่ตู้0
Absorbance (AU) Absorbance
Absorbance (AU)
0.8
0.6
0.4
0.2
0.0 250
1o
1o"
Al3+ EDTA
300
350
400
450
500
Wavelength (nm)
A 0.8
0.6
Vis UV 0.8
0.6
0.4
UV Vis
1c"
0.2
0.0
1o"
300
400
500
600
700
800
Wavelength (nm)
B
0.4
Al3+ EDTA
1c"
0.6
0.4 UV Vis
0.2
0.0 300 400 500 600 700 800 Wavelength (nm)
A
Absorbance
0.30 0.25 0.20 0.15 0.10 0.05 0.00
0
20
40
60
Time (min)
B
80
100
Emission Intensity (a.u.)
0.2
1c
0.0 300 400 500 600 700 800 900 Wavelength (nm)
C
Emission intensity (a.u.)
4000
Al3+
6
3000
5
(F-F )/F 00
4
2000
3
Free and other
metal ions
Zn2+
2
1000 1
0
Cu2+
B
Al3+ EDTA 300
1c"
200
100
1c
0
450
500
550
600
650
700
Wavelength (nm)
C
1o 1o''
2922 2922
1663 1622
567
3500
1387
3000
2500
2000
1500
-1
Wavenumber (cm )
1000
500
A
B
0.26
Y = 0.02471 - 2.346E-5* X
A
500 400 300 200 100
0 500
Vis UV
550
600
650
700
750
Wavelength (nm)
B
Absorbance (AU)
Absorbance (AU)
0.8
0.6
0.4
TBAH HCl
1o'
0.2
0.0
1o
300
400
500
600
Wavelength (nm)
A
0.8
1o'
0
500
550
600
650
700
750
Wavelength (nm)
A
100 UV
80
1o'
60
40
20
0
500
550
600
650
700
750
Wavelength (nm)
C
Emission intensity (a.u.)
Emission intensity (a.u.)
120 100
80 60 40 20
Emission intensity (a.u.)
4000 3000
Al3+ EDTA
1o"
4000 3000
Vis UV
1o"
2000
2000
1000
1o 0
450
500
550
600
650
700
Wavelength (nm)
A
1000
0
1c"
450
500
550
600
650
700
Wavelength (nm)
2+ 2+
Cd Ca
2+ 2+
Pb Hg
2+ 2+ 2+ 3+
Sr Cu Co Cr
3+
Fe
None
C
None
Al 3+ Zn 2+
K+
Mn Mg Ba Ni
2+ 2+ 2+ 2+
Cd Ca Pb
B D
2+ 2+ 2+
Hg Sr Cu Co Cr Fe
2+ 2+ 2+ 2+ 3+ 3+
Emission intensity (a.u.) Emission intensity (a.u.)
0
450 500 550 600 650 700 750
-1
Wavelength (nm)
A
4000
3+
1o+Metal ion+Al 1o+Metal ion
Emission intensity (a.u.)
3000
2000
1000
0
Blank
2+
Zn
+ 2+ 2+
K Mn Mg
2+ 2+
Ba Ni
0 0.0
0.2
0.4
0.6
0.8
1.0
Zn2+Zn2+1O
第三章：含安替比林水杨醛席夫碱 类二芳烯的合成及其性质研究
Absorbance
Emission Intensity (a.u.)
0.8
Vis UV
0.6
0.4 UV Vis
0.2
0.0
300
400
500
600
700
800
Wavelength (nm)