第一章 卤化反应练习题一、举例说明或解释以下人名反应。
1. Dalton 反应2. Hunsdriecke 反应3. Kochi 改良法4. Barton 改良法5. Finkelstein 反应6. Sandmeyer 反应7. Gattermann 反应8. Schiemann 反应二、请选出下列反应的主产物。
OHPOCl 31.( )ClA.Cl ClClB.C.D.OHClClHNOHOH SOCl 232.( )NCl OH OHA.HNCl ClB.HNCl OHC.NCl Cl Cl D.NH 3CSOHOH+POCl 3+PCl 3KF( )( )3.NN H 3CSOH OH NN H 3CSOH OH A. B.C.D.NN H 3CSClCl NN H 3CS Cl Cl NN H 3CSClClN N H 3CS OHFNN H 3CSClClNNH 3CSFFCl F FNOOHPCl 3Cl 24.( )A. B. C. D.NO ClNOOHNO ClClClNO OHClNN OHOPCl 55.( )A. B.C. D.N N NN ClO NN NN ClONN NN OHO N N NNOHOClClClNNN OHOBr 26.( )N N NNOHOBr A. B. C. D.N N NN OHOBrNNNN BrO Br NN NNOH OBrBrON N N OOO ClCl Cl 7.( )( )ONN N O O OHCl Cl ClA.B.C.D.ONN HN O OOH Cl ClON N H NOO OH Cl ClHN N HNOOOH ClOClClOOCl 2H 2O8.( )( )A. B.C. D.HOClOOClCl ClO O ClO Cl ClClO Cl HOCl O OClClCl O(HCOH)3ZnCl 29.( )OO ClA.B.C.D.OO O O Cl OO OHClNH 2NHBr 2CH 3ONa10.( )NHBrNH A.B.C.D.NH 2NBr NBr 2N Br NHBrN BrNOHOH POCl 311.( )NOH ClA.B.C.D.NClCl NCl OHNCl Cl ClPOCl 3OHOH12.( )Cl ClA.B.C.D.ClOH OHOH OH OHCl ClCl ClClClN NPOCl 313.( )A.B.C.D.NNClClN N N HN ClClCl ClCl N N ClClCl ClOOON OBr14.( )A. B. C. D.OO OOO OBrOO OO O BrBrBr BrNNOHPOCl 315.( )NNClA.B.C. D.NN Cl NN NNOHOHClCl HOPOCl 3N N OHHONH 216.( )NN ClHONH 2A. B. C.D.N N ClClHNNNClClNH 2NN OH ClNH 2ClN OH Br 2NaOH17.( )N OOBr A.B.C. D.N O OBr N O OBr BrN O OBr BrN OO H NaOCl318.( )N O OCl A.B.C.D.N O OCl N O OCH 3O ClN O OClOOHO ClO 19.( )OOHO A.B. C.D.OOHO OOHOClO ClN HONaClO20.( )N HOCl ClA.B.C. D.N ON OClClN HOClClClClOOO N OBr21.( )OO OBr A.B.C.D.OO OOO OBrOBrBrBr Br OHOSN OOBr 22.( )SBr A.B.C. D.SSS BrBr BrPOCl 3NN OHNH 223.( )N NClHO NH 2A.B. C.D.NN OHHN NN Cl HN NN Cl NH 2Cl ClO Cl 2NaCN( )24.O Cl OCNA.B.C. D.O OOOOCl CNNCOClClCNOHOSOCl 225.( )OHOA. B.C. D.ClO ClO ClClClNO 2Cl ClKF26.( )NO 2Cl FA.B.C.D.NO 2F FNO 2F ClNO 2FClCl2+2Br 2+HgO27.( )Br A.B.C.D.BrOBrSO 2Cl 26628.( )ClA.B.C.D.ClOCl+CF 3OFCFCl 3-78℃29.( )A. B.C.D.FOF FN HHCOOH+CF 3OFCFCl 330.( )N H COOH H A.B.C.D.N HHCOOH H FN HF COOH H N HCOOH H F FFC 6H 5CH CHCH 3NBS31.( )A.B.C.D.BrBrBrBrBrBrCH 3(CH 2)5CHOO O 25232.( )CH 3(CH 2)4CHBrCHO A. B.C. D.BrCH 2(CH 2)4CH 2CHO BrCH 2(CH 2)4CHBrCHOCH 3(CH 2)4CBr 2CHON NOHOHFPOCl 333.( )NNClCl FA. B.C.D.N N OHClFN N ClOHFN N OHOHFClCH 2CH 2OHKF34.( )FCH 2CH 2OHA. B. C. D.ClCH 2CH 2FFCH 2CH 2FFCHCH 2OHFOH COOHCl 26535.( )OHCOOHA.B.C. D.ClOHCOClOHCOOHClOHCOCl ClCH 2CNBr 236.( )A.CHCN BrB.CH 2CNBrC.CH 2CNBrD.CCN Br BrSCOOHCOOCH 2SOCl 237.( )A.SCOOCH 2COClSCOOCH 2COOHB.C. D.Cl SCOClO OCl SCOOHO O ClCHCOOH(H 3C)2HCCl38.( )A.ClHC CH(CH 3)2COCl B.Cl C CH(CH 3)2COOHCl C.ClHC CH(CH 3)2COOHClD.Cl HC CH(CH 3)2COClClOCOCH 3OH223339.( )COCH 3IOCOCH 3OHOCOCH 2I OHOCOCH 3OHOA. B.C. D.I IIIH 3COCH 3O240.( )A.B.C.D.H 3COCH 3OH 3COOH 3COCH 3OH 3COCH 3OBr BrBrBr。