*MSD1 SPC, time=0.168:0.493 of E:\1\DATA\00042825.D API-ES Positiv e 100
80
60
40
20
0
250
500
102.2 157.2 139.1
187.0 213.1
261.1 302.1 301.1
373.0 359.2
443.3 426.2 489.2
487.4
月桂酸聚氧乙烯酯 CH3(CH2) 10COO(EO) nH
*MSD1 SPC, time=0.495:1.310 of E:\1\DATA\00040531.D API-ES Positiv e 100
80
60
40
20
0
250
500
聚醚
750
173.4 217.3
274.4
318.3 343.5
0
200
400
600
800
m/z
m/z
1000
800
600
400
200
0
20
40
106.1
157.1 194.1
244.1
175.1 215.1
302.1
193.1
370.3 408.2
393.3
440.4 439.3 455.4 481.3 478.3
542.4 564.4 566.3
392.4 477.4
482.2 494.2 481.2
536.2 538.3
525.3
579.7 580.2
632.2 619.2 614.3 671.0 670.3 658.3 712.2 707.0 702.3 749.3 743.5 746.3
569.3
613.3 657.3 701.3 745.5
794.3 791.3 787.5 790.4
表面活性剂分析
m/z
1200
1000
800
600
400
200
0
20
261.2
305.4
365.2
349.3
409.5 443.4 453.4 499.5 482.5 497.5 533.8 532.7
393.4 437.5
481.5 525.6 531.7
570.7 569.7
597.7
629.8 636.7 620.7
CH3 CH2N HCl
CH3
*MSD1 SPC, time=0.181:0.697 of E:\1\DATA\00040537.D API-ES Positiv e
304. 5
100
Max: 2.74095e+006
80
60
305. 5 332. 5
40
643. 9
333.5
20
0
200
400
600
576.4 581.4 575.4
627.5 619.4
625.4
663.3 670.5
669.4
714.5 713.5
758.5 757.6
801.6
443.4 531.4
60
80
Max: 210537
*MSD1 SPC, time=0.166:0.864 of E:\1\DATA\00042841.D API-ES Positiv e 100
669.9
664.7
725.8 724.8 708.9
759.0
767.9
791.0 797.0 802.0
591.7 635.8
679.8
751.9
842.1 840.0 846.0
885.1 890.0
929.2 934.2
978.2
1038.2
40
60
80
575.7 619.8
663.8 707.8
800
1000
1200
m/z
磷酸酯钾盐
*MSD1 SPC, time=0.186:0.598 of E:\1\DATA\00040600.D API-ES Negativ e 100
80
60
40
20
0
169.1
113.2
200
400
600
293.5 337.4 381.5
265.4 309.4 353.4 397.5
639.8 683.9
800
O(EO)nH
904.2 921.1
948.2
1000
992.2
Max: 90925
m/z
m/z
1000
800
600
400
200
0
20
40
171.2
217.2
261.2
306.2
305.2
350.2 349.2
393.2
399.4
444.4
489.4
488.4
533.4 532.4
1312.6 1310.6
1354.7
1398.6
1000
1250
Max: 16382
1500
1470.7 1531.0
m/z
m/z
1200
1000
800
600
400
200
0
20
318.5
362.5
407.6
406.6
451.6
450.5
496.7
495.7
539.7
584.8
583.8
628.8
80
60
40
20
0
Hw (OE)O
*MSD1 SPC, time=0.223:0.469 of E:\1\DATA\00042729.D API-ES Positiv e
200
400
600
O CH2 (EO)xCOOC 17H33
O(EO)zH
261.1
305.1
349.1
394.2 393.1
438.2 437.2
655.5 654.5 719.5
761.5
830.6
60
80
Max: 102418
C17H33CON(CH2CH2OH) 2
*MSD1 SPC, time=0.142:0.708 of E:\1\DATA\00042820.D API-ES Positiv e 100
479.4
Tween 80
100
373.4
404.4
417.5
451.6
362.5 406.5
450.5
499.4 491.5
494.7 505.6
560.5 550.4 533. 614.3 601.8 591.7
7
534.8 578.8
549.5 593.7
563.7
656.7 644.7 636.8
652.7
637.8
712.8 704.8 688.8
874.0
918.2
962.2
1006.2
521.7 565.8
609.8 654.0
800
1000
Max: 47367
m/z
m/z
1200
1000
800
600
400
595.8 611.8
640.8 634.8 657.8 656.8
685.8
684.7 678.8
655.8 661.8
724.9 723.9 751.9 751.0
706.0 722.9
743.9
727.9
796.0 788.9
788.0
772.0
816.0 833.0 832.0
861.0 860.0
Max: 622966
214. 4 272. 4
80
565. 8
60
593. 8
242. 4 294. 4
40
566. 8
1136.7
571. 9 621. 8
485. 8
215. 4 273. 4
322. 5
20
0
200
400
600
800
1000
1200
m/z
十二烷基苄基二甲基氯化铵
C12H25
473. 4
Max: 28044
80
471. 5 561. 5
60
377. 2 419. 4
445. 4 475.4 485.4 489.4
503. 4 533. 4 563.4 562.5 590.5 589.5 617. 5 662.4 661.5 689. 5
40
20
771. 5
305.2
217. 1
Max: 106056
C11H23COO(EO) nH
*MSD1 SPC, time=0.606:1.383 of E:\1\DATA\00040533.D API-ES Positiv e 100
C17H33COOCnH2n+1 n=12
*MSD1 SPC, time=0.180:0.631 of E:\1\DATA\00041904.D API-ES Positiv e 100
627.8
672.8
671.9
717.0
715.9
715.0
760.0
759.0
805.0 804.0 803.0
848.1 847.1
891.1