O2N浓H2SO4
+3HO—NO2——a-
CH3
I NO2
Il+3H2O
CH2=CH2+Br2”CH2BrCH2Br
CH2=CH2+HBr尸CH3CH2Br
CH2=CH2+H2O浓H2S°4- CH3CH2OH
催化剂.
n CH2=CH2-^CH2—CH2十
催化剂
CH三CH+H2催化-CH2=CH2
CH三CH+HCl催化剂■CH2=CHCl
(30)
(28)
(29)
CH
(14)
C°°H
°H
(16)
(17)
N°2
(18)
N°2
Br
°H
Br
n°2
°Na
(31)
CH3C°°CH2CH3^CHsC°°Na
高中化学各类有机物之间的相互转化关系
光昭
CH3CH3+Br2光昭.CH3CH2Br+HBr
CH2=CH2+H2
催化剂
△
-CH3CH3
(14)
CH3
n CH2=CH
Cl
(15)
CH3
I酸性KMnO4
COOH
I I或酸性K2Cr2o7 I I
(16)
OH+NaOH
OH+Na2CO3
ONa+HCI
催化剂-一CH2—CH
_n
Cl
ONa+CO2+H2O
CaC2+2H2O» CH三CHf+Ca(OH)2
+Br2
催化剂*
A
HBr
(18)
+HO—NO2
I I+3H2
浓H2SO4
(21)C2H5—OH+HO—C2H51400CC2H5—O—C2H5+H2O
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(⑵
(13)
高中化学各类有机物之间的相互转化关系
(22)CH3CH2OH+HBr△-CH3CH2Br+H2O
(23)2CH3CH2OH+O2催化剂-2CH3CHO+2H2O
+3NH3+H2O
(26)
CH3CHO+2Cu(OH)2厶CH3COOH+CU2OJ+2H2O
(27)
CH3CHO+H2催化剂1CH3CH2OH
(28)
浓H2SO4
CH3(29)
CH3COOC2H5+H2OFHf04-CH3COOH+C2H5OH
/
T
(9)
(20)CH2—CH—
CH3—CH3 w⑵
(8)
2
Cl
Ag
CH
—n Cl
Cu2°
(ii)
(12)
(13)
(26)
_(23).Z(24)
CH3CH2—Br < »CH3—CH2—°H « " CH3CHOCH3C°°H
(27)I
(22)
(21)(19)
CH3CH2°CH2CH3CH3CH2°Na
I
CHO
+2H2
CH2OH
I
CH2OH
COOH CH20H浓H2SO4
COOH+CH2OH△*
COOHCH2OH浓H2SO4
门COOH+ nCH2OH△“
O
22
HH
cc
cc
o
+2出0
o- h+(2n-1)H2O
高中化学各类有机物之间的相互转化关系
各类有机物之间的相互转化关系
高聚酯
(40)人
CH3
ch2—ch
(6)
(3)
CH2CH2(34).CH2°^(36\CH°(37).C°°H
CH2°H(38)CH° C°°H
Br Br
CaC2
(35)
(10)
⑺
(39)
六元环状酯
CH2CH2
CH「CH
z^\
(1)
/汀
浓h2so4
Br
+
+
H2O
催化剂》
△
ONa+H2f
2-OH+2Na ”2
”一ONa+H2。
—ONa+NaHCO3
OH+NaCl
”一OH+NaHCO3
J+3HBr
Br
(19)2CH3CH2OH+2Na-2CH3CH2ONa+H2f
浓H2SO4人
(20)CH3CH2OH仃00Ca CH2=CH2f+H2O
CH3CH2OH+CUO△-CH3CHO+CU+H20
水
(32)CH3CH2Br+NaOH水一CH3CH2OH+NaBr
(33)CH3CH2Br+NaOH
CH2f+NaBr+H2O
(24)
2CH3CHO+O2
催化剂
△
-2CH3COOH
(25
)CH3CHO+2Ag(NH3)2OH
△
〜CH3COONH4+2Ag
CH2Br
(34)CH2Br+ 2Na0H
水
△ch2oh
+2NaBr
(35)
(36)
CH2BrCH2Br+2NaOH
CH2OH+O2催化剂
CH2OH2△
乙醇
肿CH三CHf+2NaBr+2H2O
CHO
CHO+2H2°
(37)CHO+O2催化剂■COOH丿CHO2△COOH
(39)
(40)
(38)
CHO
(30)2CH3COOH+2Na■ 2CH3COONa+H2f
2CH3COOH+Na2O" 2CHsCOONa+H2O
CHsCOOH+NaOHCHsCOONa+HzO
2CH3COOH+Na2CO3-2CHsCOONa+H2O+CO2f
CHsCOOH+NaHCO3”CH3COONa+H2O+CO2f
(31)CH3COOC2H5+NaOH△”CH3COONa+C2H5OH