Control Status：Issued ID：0310 WX/P-11-03 —————————————————————————————The internal control standards of chemicalmaterialPublication Data:2012-09-10 Implement Data:2012-09-20 Gaoyou satellite Cigarette Materials Co.The internal control standards of solvent and inks1ScopeThis standard provides the requirements, test methods, inspection rules, packaging, labeling, transportation and storage of gravure inks and solvent of our company .This standard applies to inks and solvents required by our Company.2Criteria for quotations and referencesThe provisions in following documents become the provisions of these specifications though quotation. As for all the quoted documents given clear indication of date, all revised papers attached to them (excluding the corrected content) or recensions do not apply to these specifications. However, all parties that reached an agreement according to these specifications are encouraged to study whether to use the up-to-date editions of these documents. As for the quoted documents not given clear indication of date, their up-to -date editions apply to these specifications.1 GB/T 191 Packaging Pictorial logo2 GB1725-79 Determination method of coating solids3 GB/T 3186 The s ampling of paint products4 GB/T 13217.1 Examination method of gravure plastic ink: Color examination5 GB/T 13217.3 Examination method of gravure plastic ink: Fineness examination6 GB/T 13217.5 Examination method of gravure plastic ink: The primary dryingexamination7 GB/T 13217.6 Examination method of gravure plastic ink: Tinting strengthexamination8 GB/T 13217.7 Examination method of gravure plastic ink: Adhesion fastness test9 YC/T 268 Determination of arsenic, lead of tipping paper and tipping base paper of cigarette.10 YC/T 316 Determination of Arsenic, lead, cadmium, chromium, nickel, mercury of tipping paper and tipping base paper of cigarette: inductively coupled plasma mass spectrometry11 YC/T 279 Determination of Arsenic, chromium, nickel of tipping paper of cigarette.12 Q/HY.CJ.166-2012 Determination of Phthalate esters of tipping paper of cigarette:GC-MS13 Q/HY.CJ.165-2012 Determination of methanal of tipping paper of cigarette: UltraPerformance Liquid Chromatography14 YC/T207 Determination of volatile organic compounds of the cigarette and wrappingpaper of boxes: Headspace - Gas Chromatography15 GB/T 14436 General Provisions of industrial products guarantee documents16 YQ15-2012 China National Tobacco Corporation corporate standardsThe list of substances which permission to use in the material for cigarette3RequirementProduct technical indicators shall conform to the Table 1Table 1 physical indexIndex Color FinenessµmViscositys(25℃)solidcontent%TintingStrength%Initialdryness%Adhesionfastness%The paper gravure inks Approximatestandardsamples≤12≥25≥2095～100 25～50 ≥93Note: The solids content of each ink varieties should meet the requirements of the contract. 3.2 Substance used in ink must comply the requirements of countries, tobacco industry licensed use list. in the production process of ink, prohibited to use of benzene soluble inks and metal complex dyes; prohibit adding phthalate plasticizers; ethanol solvent used must comply with the requirements of GB10343.3.3 Health indicators of ink using scraping sample test, the health indicators of product shall comply with Table 2,3,4.Table 2 Heavy metalItemArsenic（㎎/㎏）Lead(㎎/㎏）Mercury(㎎/㎏）Cadmium(㎎/㎏）Chromium(㎎/㎏）Nickel(㎎/㎏）The papergravure inks≤0.6≤3.0≤0.6≤0.6≤10.0≤6.0Note: For special and less dosage ink, heavy metals in accordance with the requirements of the special provisions, such as purple, red ink arsenic content is below 3ppm. Chromium content is below 30ppm.Table 3 VOCs表4邻苯二甲酸酯类ItemUnitIndexdimethyl phthalate ppm not detectablediethyl phthalate ppmDiisobutyl phthalate ppm not detectable dibutyl phthalate ppmnot detectablePhthalate (2 - methoxy) ethyl ester ppm Phthalate (4 - methyl - 2 - amyl) ethyl esterppm Phthalate (2 -) ethoxy ethyl esterppm diamyl phthalateppmName of indexUnitIndexV olatileOrganic Compoundsbenzene mg/m 2 Not detectablemethylbenzene mg/m 2 ≤0.12 ethylbenzene mg/m 2 ≤0.12 xylene mg/m 2 ≤0.12 methyl alcohol mg/m 2 ≤0.8normal propyl alcohol mg/m 2 ≤2.5isopropyl alcohol mg/m 2 n-butyl alcohol mg/m 2 propylene glycol monoethyl ether mg/m 2 formaldehyde g/kg ≤0.010 propylene glycol monomethyl ether mg/m 2 ≤1.8 n-butyl acetate mg/m 2 ≤0.5 ethyl acetate mg/m 2 Total ≤2.5n-propyl acetate mg/m 2 acetic acid isopropylester mg/m 2 acetone mg/m 2 Total ≤2.0butanonemg/m 2 4-methyl-2-pentanonemg/m 2cyclohexanone mg/m 2Dihexylphthalate ppmButyl benzyl phthalate ppmPhthalate (2 - butoxy) ethyl ester ppmDicyclohexyl phthalate ppmPhthalate (2 -) ethyl ester ppmDiphenyl phthalate ppmDi-n-octyl ortho-phthalate ppmDiisonoyl adipate ppmDiisononyl phthalate ppmNote：other individual event ≤20ppm，total ≤50ppm，in which special and less dosage ink, the requirements of phthalate esters in accordance with the special provisions, such as: purple, black ink dimethyl phthalate, di-iso-butyl phthalate, phthalic carboxylic acid ester content should be below 10ppm.4SamplingSampling according to GB / T 3186 provisions of paint products.5Testing standard5.1ColorInspection according to GB / T 13217.1.5.2FitnessInspection according to GB / T 13217.3.5.3ViscosityInspection according to GB / T 13217.4-2008.5.4Coating Solid contentInspection according to GB1725-79 Coating solid content measurement。