应用电化学全套课件496p
electrochemical processes and reactions; 4. 电话学研究的策略与思想-The philosophy and strategies in
electrochemical studies
电化学发展史
History of more than two centuries
Methods for
studying the
...
interface
电化学作为技术的研究范围
energy Batteries
Electrolysis & electrosynthesis
resources
Electrochemical protection of materials
environments
常州大学研究生课程
应用电化学
主要参考书
1. A. J. Bard著,邵元华等译,《电化学方法-原理和应用》, 化学工 业出版社, 2005年
2. 查全性著,《电极过程动力学导论》科学出版社,2002年,第三版 3. 李荻编 《电化学原理》北京航天航空大学出版社,1999年 4. David K. Gosser, Jr. Cyclic voltammetry - simulation and analysis of
Thermodyna-
mics 1834 法拉第 Faraday (England )
Faraday law
1870 Helmholtz (Germany ) theory for electric double layer
Electroche- 1889 能斯特 Nernst( Germanny)
Quantum and computation mechanics(theoretic and computational electrochemistry)
Material science (material electrochemistry) Nanoscience and nanotechnology (Nano-electrochemistry) ......
of matters
Electric power
Energy conversion
Chemical power
电化学作为基础科学的研究范围
Solid-liquid interface
Interfacial charge transfer
Mass transport
Electrochemistry
Interfacial adsorption
Electric phenomena /
processes
Electrochemical reactions
Chemical phenomena /
processes
Charge formation & transfer
Electrochemical Science &
Technologies
formation & transformation
mistry
现代电化学
涉及的学科领域:
Chemistry, Physics, Mathematics Spectroscopes (spectroscopic electrochemistry) Biological science (bio-electrochemistry) Environmental science(environmental electrochemistry)
Nernst equation
mical kinetics
1905 塔菲尔 Tafel (Germanny )
Tafel equation
1920s-70s Butler, Vomer, Frumkin, Bockris, Bard ….
Modern electroche
1970s-
Electrochemistry at molecular and atomic level
reaction mechanisms 1993 VCH publishers, Inc.
课程内容
1. 电化学基础理论 2. 电催化动力学 3. 锂离子电池 4. 电化学电容器 5. 燃料电池
第一章 电化学基础理论
1. 电化学发展简史-A historical view of electrochemical science 2. 电化学研究对象-What does electrochemistry deal with ? 3. 电化学过程和电化学反应的特点-The features of
• 研究发生在电极与电解质界面的现象、过程和反应(The phenomena, processes and reactions occurring at interface between an electronic conductor (electrode) and an ionic conductor (electrolyte) )
• 研究化学能与电能之间相互转换的原理与技术(The laws and the technologies conቤተ መጻሕፍቲ ባይዱerning the conversion between chemical energy and electrical energy)
• 研究化学现象与电现象的相关性(Interrelation between chemical phenomena (chemical reactions, chemical changes, etc.) and electric phenomena (charge, current, potential, electric field, etc.))
1791 伽伐尼Galvani (Italy) biological electric phenomena
1799 伏打Volta ( Italy ) Volta cell
Electrochemi- 1800 尼科尔森-卡莱尔 Nicholson - Carlisle(England)
cal
water electrolysis
Electrochemistry
Electrochemical treatments of wastes
Electrochemical sensors
health
Electrochemical therapy
电化学研究对象 What does Electrochemistry deal with ?